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Pure Appl. Chem. Vol. 76, No. 3, pp. 453-695 (2004)

Pure and Applied Chemistry

Vol. 76, Issue 3

Organometallic Chemistry Directed Towards Organic Synthesis

Plenary and invited lectures presented at the 12th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS-12), Toronto, Ontario, Canada, 6-10 July 2003

Preface, W. Tam

Metal cyclopropyl carbenes in the reactions of alkynes with alkenes and furans
A. M. Echavarren, M. M�ndez, M. P. Mu�oz, C. Nevado, B. Mart�n-Matute, C. Nieto-Oberhuber, and D. J. C�rdenas
p. 453 [Abstract] [full text - pdf 296KB]

Rhodium-catalyzed asymmetric addition of aryl- and alkenylboron reagents to electron-deficient olefins
T. Hayashi
p. 465 [Abstract] [full text - pdf 329KB]

Synthetic applications of planar chiral cationic nu3-allylmolybdenum complexes
P. Kocienski, R. Bell, E. Bourque, J. A. Christopher, J. Cooksey, A. Gunn, A. Kuhl, Y. Li, S. Uppal, and J. Yuen
p. 477 [Abstract] [full text - pdf 334KB]

Application of allylic substitutions in natural products synthesis
G. Helmchen, M. Ernst, and G. Paradies
p. 495 [Abstract] [full text - pdf 319KB]

Development of catalysts for the hydroamination of olefins
J. F. Hartwig
p. 507 [Abstract] [full text - pdf 284KB]

New regio-, stereo-, diastereo- and enantioselective one-pot reactions mediated by organometallic derivatives
N. Chinkov, G. Sklute, H. Chechik, A. Abramovitch, D. Amsallem, J. Varghese, S. Majumdar, and I. Marek
p. 517 [Abstract] [full text - pdf 485KB]

Negative nonlinear effect in aquo palladium catalysis depending on tropos biphenylphosphine ligand chirality controlled by chiral diaminobinaphthyl activator
K. Mikami, K. Aikawa, and M. Yamanaka
p. 537 [Abstract] [full text - pdf 210KB]

Asymmetric catalytic synthesis of polyketones and polycarbonates
K. Nozaki
p. 541 [Abstract] [full text - pdf 208KB]

Development of a new methodology for the preparation of optically active alcohols
P. G. Andersson
p. 547 [Abstract] [full text - pdf 201KB]

Stereochemistry of epoxide carbonylation using bimetallic Lewis acid/metal carbonyl complexes
Y. D. Y. L. Getzler, V. Mahadevan, E. B. Lobkovsky, and G. W. Coates
p. 557 [Abstract] [full text - pdf 243KB]

Dual role of nucleophiles in palladium-catalyzed Heck, Stille, and Sonogashira reactions
A. Jutand
p. 565 [Abstract] [full text - pdf 304KB]

Application of C-H and C-C bond activation in organic synthesis
C.-H. Jun and J. H. Lee
p. 577 [Abstract] [full text - pdf 293KB]

Coordination of the Trost modular ligand to palladium allyl fragments: Oligomers, monomers and memory effects in catalysis
G. C. Lloyd-Jones, S. C. Stephen, I. J. S. Fairlamb, A. Martorell, B. Dominguez, P. M. Tomlin, M. Murray, J. M. Fernandez, J. C. Jeffery, T. Riis-Johannessen, and T. Guerziz
p. 589 [Abstract] [full text - pdf 270KB]

New methods for the synthesis of heterocyclic compounds
A. Caiazzo, S. Dalili, C. Picard, M. Sasaki, T. Siu, and A. K. Yudin
p. 603 [Abstract] [full text - pdf 254KB]

Mechanistic insights into perfluoroaryl borane-catalyzed allylstannations: Toward asymmetric induction with chiral boranes
D. J. Morrison, J. M. Blackwell, and W. E. Piers
p. 615 [Abstract] [full text - pdf 254KB]

New insights into the mechanism of molybdenum-catalyzed asymmetric alkylation
S. W. Krska, D. L. Hughes, R. A. Reamer, D. J. Mathre, M. Palucki, N. Yasuda, Y. Sun, B. M. Trost
p. 625 [Abstract] [full text - pdf 288KB]

Recent advances in catalyst immobilization using supercritical carbon dioxide
W. Leitner
p. 635 [Abstract] [full text - pdf 314KB]

Substrate scope in the olefin cyclopropanation reaction catalyzed by m-oxo-bis[(salen)iron(III)] complexes
S. K. Edulji and S. T. Nguyen
p. 645 [Abstract] [full text - pdf 158KB]

Recent advances in transition metal-catalyzed or -mediated cyclization of 2,3-allenoic acids: New methodologies for the synthesis of butenolides
S. Ma
p. 651 [Abstract] [full text - pdf 212KB]

3-Halopropenyl esters as precursors of a new class of oxygen-substituted allylic organometallic compounds: Applications in organic synthesis
M. Lombardo, S. Licciulli, and C. Trombini
p. 657 [Abstract] [full text - pdf 332KB]

Palladium-catalyzed alkylation of unactivated olefins
R. A. Widenhoefer
p. 671 [Abstract] [full text - pdf 219KB]

Heterogeneous asymmetric catalysis
M. Lemaire
p. 679 [Abstract] [full text - pdf 265KB]

Stereoselective chromium- and molybdenum-mediated transformations of arenes
E. P. K�ndig, R. Cannas, C.-H. Fabritius, G. Grossheimann, M. Kondratenko, M. Laxmisha, S. Pache, H. Ratni, F. Robvieux, P. Romanens, and S. Tchertchian
p. 689 [Abstract] [full text - pdf 258KB]


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