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Pure Appl. Chem. Vol. 73, No. 1, pp. 119-128 (2001)

Pure and Applied Chemistry

Vol. 73, Issue 1

Rapid screening and combinatorial methods in homogeneous organometallic catalysis*

Jennifer A. Loch and Robert H. Crabtree**

Department of Chemistry, Yale University, P.O. Box 208107, New Haven, CT 06520-8107, USA

Abstract: Methods are discussed for rapid screening of soluble and polymer-bound homo-geneous catalysts for activity. A polymer-bound phosphine library is synthesized, and a modular tridentate pincer CNC bis-carbene Pd complex is described. The possibility of C-bound His in metalloenzymes is raised.

* Lectures presented at the International Symposium on Green Chemistry, Delhi, India, 10-13 January 2001. Other presentations are published in this issue, pp. 77-203.
** Corresponding author.

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